The 4D Camera: an 87 kHz direct electron detector for scanning/transmission electron microscopy
Citation (APA 7)
The 4D Camera: an 87 kHz direct electron detector for scanning/transmission electron microscopy P Ercius, IJ Johnson, P Pelz, BH Savitzky, L Hughes, HG Brown, … arXiv preprint arXiv:2305.11961
Abstract
Four-dimensional scanning transmission electron microscopy (4D-STEM) has recently gained widespread attention for its ability to image atomic electric fields with sub-{}ngstrom spatial resolution. These electric field maps represent the integrated effect of the nucleus, core electrons and valence electrons, and separating their contributions is non-trivial. In this paper, we utilized simultaneously acquired 4D-STEM center of mass (CoM) images and annular dark field (ADF) images to determine the electron charge density in monolayer MoS2. We find that both the core electrons and the valence electrons contribute to the derived electron charge density. However, due to blurring by the probe shape, the valence electron contribution forms a nearly featureless background while most of the spatial modulation comes from the core electrons. Our findings highlight the importance of probe shape in interpreting charge densities derived from 4D STEM.